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potassium hydroxide : ウィキペディア英語版
potassium hydroxide

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Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.
Along with sodium hydroxide (NaOH), this colorless solid is a prototypical strong base. It has many industrial and niche applications; most applications exploit its reactivity toward acids and its corrosive nature. An estimated 700,000 to 800,000 tonnes were produced in 2005. Approximately 100 times more NaOH than KOH is produced annually.〔H. Schultz, G. Bauer, E. Schachl, F. Hagedorn, P. Schmittinger "Potassium Compounds" in Ullmann’s Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. 〕 KOH is noteworthy as the precursor to most soft and liquid soaps as well as numerous potassium-containing chemicals.
==Properties and structure==
Potassium hydroxide can be found in pure form by reacting sodium hydroxide with impure potassium. Potassium hydroxide is usually sold as translucent pellets, which will become tacky in air because KOH is hygroscopic. Consequently, KOH typically contains varying amounts of water (as well as carbonates, see below). Its dissolution in water is strongly exothermic, meaning the process gives off significant heat. Concentrated aqueous solutions are sometimes called potassium lyes. Even at high temperatures, solid KOH does not dehydrate readily.〔Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.〕
Potassium hydroxide solutions with concentrations of approximately 0.5 to 2.0% are irritating when coming in contact with the skin, while concentrations higher than 2% are corrosive.〔(Potassium hydroxide, SIDS Initial Assessment Report For SIAM 13. Bern, Switzerland, 6-9 November 2001. ) By Dr. Thaly LAKHANISKY. Date of last Update: February 2002〕

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